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| Experimental study on the strength and environmental properties of Ni and Zn contaminated soil stabilized by SPB and SPC binders |
| FENG Yasong1,2,XIA Weiyi1,2,DU Yanjun1,2,ZHANG Liming1,2,WU Jian1,2,LIU Rongqin1,2,#br# CHEN Weiyan3,ZHAO Jieli3 |
| (1. Institute of Geotechnical Engineering,Southeast University,Nanjing,Jiangsu 210096,China;2. Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety,Southeast University,Nanjing,Jiangsu 210096,China;3. Jiangsu Sentay Environmental Science and Technology Co.,Ltd.,Nanjing,Jiangsu 210007,China) |
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Abstract The systematic investigation on the strength and environmental safety properties of the SPB and SPC stabilized soil is presented in this paper. The field soil which has been industrial contaminated with nickel(Ni) and zinc(Zn) is studied. The SPB binder is composed of superphosphate and cement-activated steel slag and the SPC binder is composed of superphosphate and quicklime. The stabilized soils were tested for the unconfined compression strength,dry density,soil pH,acid neutralization capacity,toxic leaching characteristics and contaminant speciation varying with dosages and curing periods. The results demonstrate that the addition of two binders increases the unconfined compressive strength and soil pH,but reduces the toxicity leaching concentration of Ni and Zn. These results are interpreted based on the variations in chemical speciation of Ni and Zn and the capacity index of acid buffer of the stabilized soils. It was also found that the SPC stabilized soil had a lower pH value than that of PC under curing of 28 days. The SPC shows higher immobilization efficiency than PC at early curing. Overall,this study demonstrates that the SPB and SPC binders have positive effects on the immobilization of the heavy metal and the strength of the stabilized soils.
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[1] 杜延军,金 飞,刘松玉,等. 重金属工业污染场地固化/稳定处理研究进展[J]. 岩土力学,2011,32(1):116–124.(DU Yanjun,JIN Fei,LIU Songyu,et al. Review of stabilization/solidification technique for remediation of heavy metals contaminated lands[J]. Rock and Soil Mechanics,2011,32(1):116–124.(in Chinese))
[2] 刘松玉,詹良通,胡黎明,等. 环境岩土工程研究进展[J]. 土木工程学报,2016,49(3):6–30.(LIU Songyu,ZHAN Liangtong,HU Liming,et al. Environmental geotechnics:state-of-the-art of theory,testing and application to practice[J]. China Civil Engineering Journal,2016,49(3):6–30.(in Chinese))
[3] 骆永明. 中国土壤环境污染态势及预防、控制和修复策略[J]. 环境污染与防治,2009,31(12):27–31.(LUO Yongming. Trends in soil environmental pollution and the prevention-controlling-remediation strategies in China[J]. Environmental Pollution and Control,2009,31(12):27–31.(in Chinese))
[4] DU Y J,JIANG N J,LIU S Y,et al. Engineering properties and microstructural characteristics of cement solidified zinc-contaminated kaolin clay[J]. Canadian Geotechnical Journal,2014,51(3):289–302.
[5] SPENCE R D,SHI C. Stabilization and solidification of hazardous,radioactive and mixed wastes[M]. Florida,USA:CRC Press,2002:1–5.
[6] HARBOTTLE M J,Al-TABBAA A,EVANS C W. A comparison of the technical sustainability of in situ stabilization/solidification with disposal to landfill[J]. Journal of Hazardous Materials,2007,141:430–440.
[7] QIAO X C,POON C S,CHEESEMAN C R. Investigation into the stabilization/solidification performance of Portland cement through cement clinker phases[J]. Journal of Hazardous Materials,2007,139(2):238–243.
[8] 邵 俐,刘 佳,丁 勇,等. 水泥固化镍污染土的强度和微观结构特性研究[J]. 水资源与水工程学报,2014,(2):75–80.(SHAO Li,LIU Jia,DING Yong,et al. Research on strength and microstructure characteristics of cement solidified nickel contaminated soil[J]. Journal of Water Resources and Water Engineering,2014,(2):75–80.(in Chinese))
[9] DU Y J,WEI M L,REDDY K R,et al. Effect of acid rain pH on leaching behavior of cement stabilized lead-contaminated soil[J]. Journal of Hazardous Materials,2014,271:131–140.
[10] WEI M L,DU Y J,REDDY K R,et al. Effects of freeze-thaw on characteristics of new KMP binder stabilized Zn and Pb contaminated soils[J]. Environmental Research and Pollution Research,2015,22(24):19 473–19 484.
[11] 查甫生,刘晶晶,许 龙,等. 水泥固化重金属污染土干湿循环特性试验研究[J]. 岩土工程学报,2013,35(7):1 246–1 252.(ZHA Fusheng,LIU Jingjing,XU Long,et al. Cyclic wetting and drying tests on heavy metal contaminated soils solidified/stabilized by cement[J]. Chinese Journal of Geotechnical Engineering,2013,35(7):1 246–1 252.(in Chinese))
[12] COTTER-HOWELLE J,CAPORN S. Remediation of contaminated land by formation of heavy metal phosphates[J]. Applied Geochemistry,1996,11(1):335–342.
[13] CAO X,LIANG Y,ZHAO L,et al. Mobility of Pb,Cu,and Zn in the phosphorus-amended contaminated soils under simulated landfill and rainfall conditions[J]. Environmental Science and Pollution Research,2013,20(9):5 913–5 921.
[14] DU Y J,WEI M L,REDDY K R,et al. New phosphate-based binder for stabilization of soils contaminated with heavy metals:leaching,strength and microstructure characterization[J]. Journal of Environmental Management,2014,146:179–188.
[15] DU Y J,WEI M L,REDDY R K,et al. Effect of carbonation on leachability,strength and microstructural characteristics of KMP binder stabilized Zn and Pb contaminated soils[J]. Chemosphere,2016,144:1 033–1 042.
[16] MULLINS G L,SIKORA F J. Effect of soil pH on the requirement for water-soluble phosphorus in triple superphosphate fertilizers[J]. Nutrient Cycling in Agroecosystems,1994,40(3):207–214.
[17] SHI C J. Steel slag-its production,processing,characteristics and cementitious properties[J]. Journal of Materials in Civil Engineering,2004,16(3):230–236.
[18] POH H Y,GHATAORA G S,GHAZIREH N. Soil stabilization using basic oxygen steel slag fines[J]. Journal of Materials in Civil Engineering,2006,18(2):229–240.
[19] MALASAVAGE N E,JAGUPILLA S,GRUBB D G,et al. Geotechnical performance of dredged material-steel slag fines blends:laboratory and field evaluation[J]. Journal of Geotechnical and Geoenvironmental Engineering,2012,138(8):981–991.
[20] MANSO J M,ORTEGA-LOPEZ V,POLANCO J A,et al. The use of ladle furnace slag in soil stabilization[J]. Construction and Building Materials,2013,40:126–134.
[21] LUAN F,XIE L,SHEMG J,et al. Reduction of nitrobenzene by steel convert slag with Fe(II) system:The role of calcium in steel slag[J]. Journal of Hazardous Materials,2012,217:416–421.
[22] SONG G,WU Y,CHEN X,et al. Adsorption performance of heavy metal ions between EAF steel slag and common mineral adsorbents[J]. Desalination and Water Treatment,2014,52(37/39):7 125–7 132.
[23] FRANCISCA F M,GLATSTEIN D A. Influence of pH on cadmium,copper,and lead removal from wastewater by steel slag[J]. Desalination and Water Treatment,2016,57(45):21 610–21 618.
[24] SHI C,FERNANDEZ-JIMENEZ A. Stabilization/solidification of hazardous and radioactive wastes with alkali-activated cements[J]. Journal of Hazardous Materials,2006,137(3):1 656–1 663.
[25] SERRAJ S,BOUDEVILLE P,TEROL A. Effect of mechanical grinding of MCPM and CaO mixtures on their composition and on the mechanical properties of the resulting self-setting hydraulic calcium phosphate cements[J]. Journal of Materials Science:Materials in Medicine,2001,12(1):45–50.
[26] WANG X H,MA J B,WANG Y N,et al. Reinforcement of calcium phosphate cements with phosphorylated chitin[J]. Chinese Journal of Polymer Science,2002,20(4):325–332.
[27] EL ASRI S,LAGHZIZIL A,CORADIN T,et al. Conversion of natural phosphate rock into mesoporous hydroxyapatite for heavy metals removal from aqueous solution[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2010,362(1):33–38.
[28] BARRALET J E,LILLEY K J,GROVER L M,et al. Cements from nanocrystalline hydroxyapatite[J]. Journal of Materials Science:Materials in Medicine,2004,15(4):407–411.
[29] USEPA. Technology performance review:selecting and using solidification/stabilization treatment for site remediation[R]. Washington:USEPA,2009.
[30] BARNARD L H,BONE B D,HILLS C D. Guidance on the use of stabilisation/solidification for the treatment of contaminated materials[R]. Bristol,U K:Environment Agency,2003.
[31] DU Y J,JIANG N J,SHEN S L,et al. Experimental investigation of influence of acid rain on leaching and hydraulic characteristics of cement-based solidified/stabilized lead contaminated clay[J]. Journal of Hazardous Materials,2012,225:195–201.
[32] PUEYO M,RAURET G,LUCK D,et al. Certification of the extractable contents of Cd,Cr,Cu,Ni,Pb and Zn in a freshwater sediment following a collaboratively tested and optimised three-step sequential extraction procedure[J]. Journal of Environmental Monitoring,2001,3(2):243–250.
[33] NEMATI K,BAKAR N K A,ABAS M R,et al. Speciation of heavy metals by modified BCR sequential extraction procedure in different depths of sediments from Sungai Buloh,Selangor,Malaysia[J]. Journal of Hazardous Materials,2011,192(1):402–410.
[34] RAURET G,LOPEZ-SANCHEZ J F,SAHUQUILLO A,et a1. Improvement of the BCR three-step sequential extraction procedure prior to the certification of new sediment and soil reference materials[J]. Journal of Environmental Monitoring,1999,(1):57–61.
[35] STEGEMANN J A,COTE P L. Investigation of test methods for solidified waste evaluation,appendix B:test methods for solidified waste evaluation[R]. Burlington,Ontario,Canada:Environment Canada Manuscript Series,1991:49–52.
[36] ZHANG H Y,KAMON M,KATSUMI T. Effect of acid buffering capacity on the long-term mobility of heavy metals in clay liner[J]. Journal of the Japanese Geotechnical Society:Soils and Foundations,2004,44(6):111–120.
[37] RAO S N,RAJASEKARAN G. Reaction products formed in lime-stabilized marine clays[J]. Journal of Geotechnical Engineering,1996,122(5):329–336.
[38] 殷宗泽. 土工原理[M].北京:中国水利水电出版社,2007:13–27.(YIN Zongze. Principles of geotechnical engineering[M]. Beijing:China Water Power Press,2007:13–27.(in Chinese))
[39] 夏威夷,魏明俐,杜延军,等. 有机物污染场地浅层异位固化稳定化试验研[J]. 岩土工程学报,2016,38(3):510–517.(XIA Weiyi,WEI Mingli,DU Yanjun,et al. Experimental study on ex-situ S/S for shallow soil of organically contaminated site[J]. Chinese Journal of Geotechnical Engineering,2016,38(3):510–517.(in Chinese))
[40] 杜延军,蒋宁俊,王 乐,等. 水泥固化锌污染高岭土强度及微观特性研究[J]. 岩土工程学报,2012,34(11):2 114–2 120.(DU Yanjun,JIANG Ningjun,WANG Le,et al. Strength and microstructure characteristics of cement-based solidified/stabilized zinc-contaminated kaolin[J]. Chinese Journal of Geotechnical Engineering,2012,34(11):2 114–2 120.(in Chinese))
[41] 陈 蕾,刘松玉,杜延军,等. 水泥固化重金属铅污染土的强度特性研究[J]. 岩土工程学报,2010,32(12):1 898–1 903.(CHEN Lei,LIU Songyu,DU Yanjun,et al. Unconfined compressive strength properties of cement solidified/stabilized lead-contaminated soils[J]. Chinese Journal of Geotechnical Engineering,2010,32(12):1 898– 1 903.(in Chinese))
[42] 湖南省环境保护科学研究院. DB 43T 1165—2016 重金属污染场地土壤修复标准[S]. 长沙:湖南科学技术出版社,2016.(Hunan Research Academy of Environmental Sciences. DB 43T 1165—2016 Standards for soil remediation of heavy metal contaminated sites[S]. Changsha:Hunan Science and Technology Press,2016.(in Chinese))
[43] HAN F X,BANIN A,KINGERY W L,et al. New approach to studies of heavy metal redistribution in soil[J]. Advances in Environmental Research,2003,8(1):113–120.
[44] YONG R N. Geoenvironmental engineering:Contaminated soils,pollutant fate,and mitigation[M]. Boca Raton:CRC Press,2000:101–148.
[45] LOMBI E,HAMON R E,MCGRATH S P,et al. Lability of Cd,Cu,and Zn in polluted soils treated with lime,beringite,and red mud and identification of a non-labile colloidal fraction of metals using isotopic techniques[J]. Environmental Science and Technology,2003,37(5):979–984.
[46] 陈 蕾. 水泥固化稳定重金属污染土机制与工程特性研究[博士学位论文][D]. 南京:东南大学,2010.(CHEN Lei. Research of mechanism and properties of cement stabilized/ solidified heavy metal contaminated soils[Ph. D. Thesis][D]. Nanjing:Southeast University,2010.(in Chinese)) |
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