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| Experimental research on engineering characteristics of manganese residue |
| LI Shilong1,2,WEI Zuoan1,2,LU Ting1,2,WANG Wensong1,2,YANG Yonghao1,ZHAO Junkang1,2 |
| (1. State Key Laboratory of Coal Mine Disaster Dynamics and Control,Chongqing University,Chongqing 400044,China;2. School of Resources and Safety,Chongqing University,Chongqing 400044,China) |
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Abstract Electrolytic manganese residue,also called manganese slag,is a solid waste produced during the electrolytic manganese process. The engineering mechanical properties of manganese slag have great significance for analyzing the stability of manganese slag dams. Through a large number of indoor tests,the soluble salt components in the manganese slag were determined,and the physical and mechanical properties of the manganese slag before and after desalination were tested. The test results show that the soluble salt contained in the manganese slag is sulfate,and the sulfate content is 10.64%﹣13.98%. Thus,the manganese residue belongs to super-saline soil. Due to the presence of crystal water in sulfate,the recommended drying condition is temperature 55 ℃ and time more than 4 d. The particle size gradation of desalted manganese slag is worse than that of original manganese slag. After the manganese slag is desalted,the liquid-plastic limit,optimal moisture content,permeability coefficient and consolidation coefficient increases. But the maximum dry density and compression modulus decreases. With the increase of dry density and water content,the stress-strain relationship of manganese slag gradually changed from strain hardening type to strain softening type. The peak shear strength decreases with the loss of salt. The values of c and φ increase with the increase of dry density or decrease of water content.
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| [1] ZHOU C B,DU B,WANG N F,et al. Preparation and strength property of autoclaved bricks from electrolytic manganese residue[J]. Journal of Cleaner Production,2014,84:707–714. [2] CHANG J,CHANDRASEKAR S,SUN X X,et al. Optimization of microwave-assisted manganese leaching from electrolyte manganese residue[J]. Green Processing and Synthesis,2019,9(1):1–11. [3] 蓝际荣,孙 燕,潘 滢,等. 球磨与助剂强化选择性回收电解锰渣中的锰[J]. 中国有色金属学报,2019,29(8):1 749–1 755. (LAN Jirong,SUN Yan,PAN Ying,et al. Selective recovery of manganese in electrolytic manganese slag by ball milling and additives enhancement[J]. Chinese Journal of Nonferrous Metals,2019,29(8):1 749–1 755.(in Chinese)) [4] LV Y,LI J,YE H P,et al. Bioleaching of silicon in electrolytic manganese residue using single and mixed silicate bacteria[J]. Bioprocess and Biosystems Engineering,2019,42(11):1 819–1 828. [5] 中华人民共和国国家标准编写组. GB18599—2001 一般工业固体废物贮存、处置场污染控制标准[S]. 北京:中国环境科学出版社,2001.(The National Standard Compilation Group of the People′s Republic of China. GB18599—2001 General industrial solid waste storage and disposal site pollution control standard[S]. Beijing:China Environmental Science Press,2001.(in Chinese)) [6] 袁泽川. 尾矿的动力应力﹣应变特性[J]. 工业建筑,2017,47(10):139–145.(YUAN Zechuan. Dynamic stress-strain characteristics of tailings[J]. Industrial Construction,2017,47(10):139–145.(in Chinese)) [7] 周长波,何 捷,孟俊利,等. 电解锰废渣综合利用研究进展[J]. 环境科学研究,2010,23(8):1 044–1 048.(ZHOU Changbo,HE Jie,MENG Junli,et al. Research progress of comprehensive utilization of electrolytic manganese waste residue[J]. Environmental Science Research,2010,23(8):1 044–1 048.(in Chinese)) [8] 闫国孟,彭 兵,柴立元,等. 锰渣的理化特性及煅烧特性[J]. 中南大学学报:自然科学版,2015,46(7):2 419–2 425.(YAN Guomeng,PENG Bing,CHAI Liyuan,et al. Physical and chemical properties and calcination properties of manganese slag[J]. Journal of Central South University:Natural Science,2015,46(7): 2 419–2 425.(in Chinese)) [9] 欧阳玉祝,李佑稷,李 辉,等. 助剂作用下不同浸取方法从电解锰渣中回收锰(英文)[J]. 稀有金属材料与工程,2008,37(增2):603–608.(OUYANG Yuzhu,LI Youji,LI Hui,et al. Recovery of manganese from electrolytic manganese residue by different leaching techniques in the presence of accessory ingredients[J]. Rare Metal Materials and Engineering,2008,37(Supp.2):603–608.(in Chinese)) [10] 秦茂钊. 锰三角地区电解锰尾矿库渣场的环境岩土分析[J]. 环境工程,2014,32(增1):658–660.(QIN maozhao. Environmental geotechnical analysis of the electrolytic manganese tailings slag yard in the manganese triangle[J]. Environmental Engineering,2014,32 (Supp.1):658–660.(in Chinese)) [11] ZHAO R,HAN F L. Preparation of geopolymer using electrolytic manganese residue[J]. Key Engineering Materials,2013,2820:130–133. [12] 王运正,王吉坤,谢红艳. 现代锰冶金[M]. 北京:冶金工业出版社,2015:138–148.(WANG Yunzheng,WANG Jikun,XIE Hongyan. Modern manganese metallurgy[M]. Beijing:Metallurgical Industry Press,2015:138–148.(in Chinese)) [13] NING D,WANG F,ZHOU C B,et al. Analysis of pollution materials generated from electrolytic manganese industries in China[J]. Resources,Conservation and Recycling,2009,54(8):506–511. [14] 蔡 林. 电解金属锰工业存在的问题与对策分析[J]. 低碳世界,2015,36:107–108.(CAI Lin. Problems and countermeasures of electrolytic metal manganese industry[J]. Low Carbon World,2015,36:107–108.(in Chinese)) [15] 中华人民共和国国家标准编写组. GB/T50123—2019 土工试验方法标准[S]. 北京:中国计划出版社,2019.( The National Standard Compilation Group of the People′s Republic of China. GB / T50123—2019 Geotechnical Test Method Standard [S]. Beijing:China Planning Press,2019.(in Chinese)) [16] 柴林涛,乔秀臣,秦 东. 结晶硫酸铝脱水过程中晶型与形貌的转变[J]. 无机盐工业,2016,48(11):17–20.(CHAI Lintao,QIAO Xiuchen,QIN Dong. Crystal form and morphology change during dehydration of crystalline aluminum sulfate[J]. Inorganic Salt Industry,2016,48 (11):17–20.(in Chinese)) [17] 李国英,贺春宝. 硫酸镁的性质和用途及生产方法[J]. 山西化工,2008,(1):49–51.(LI Guoying,HE Chunbao. The properties,uses and production methods of magnesium sulfate[J]. Shanxi Chemical Industry,2008,(1):49–51.(in Chinese)) [18] 路 停,魏作安,王文松,等. 磷石膏的动力学特性试验研究[J]. 振动与冲击,2020,39(14):264–271.(LU Ting,WEI Zuoan,WANG Wensong,et al. Experimental study on the dynamic characteristics of phosphogypsum [J]. Journal of Vibration and Shock,2020,39(14):264–271. (in Chinese)) [19] 包卫星,李志农,罗炳芳. 公路工程粗粒盐渍土易溶盐试验方法研究[J]. 岩土工程学报,2010,32(5):792–797.(BAO Weixing,LI Zhinong,LUO Bingfang. Study on soluble salt test method of coarse-grained saline soil in highway engineering[J]. Journal of Geotechnical Engineering,2010,32 (5):792–797.(in Chinese)) [20] 付江涛,栗岳州,胡夏嵩,等. 含盐量对亚硫酸盐渍土抗剪强度影响的试验[J]. 农业工程学报,2016,32(6):155–161.(FU Jiangtao,LI Yuezhou,HU Xiasong,et al. Experiment on the influence of salt content on the shear strength of sulfite saline soil[J]. Journal of Agricultural Engineering,2016,32(6):155–161.(in Chinese)) [21] 冯忠居,成 超,王延武,等. 荒漠极干旱区板块状盐渍土微结构变化对其强度特性的影响分析[J]. 岩土工程学报,2011,33(7): 1 142–1 145.(FENG Zhongju,CHENG Chao,WANG Yanwu,et al. Analysis of the influence of microstructure changes of plate-shaped saline soil on its strength characteristics in desert and arid area[J]. Journal of Geotechnical Engineering,2011,33(7):1 142–1 145.(in Chinese)) [22] 闫亚景,文宝萍,黄志全,等. 易溶盐对兰州非饱和重塑黄土抗剪强度的影响[J]. 岩土力学,2017,38(10):2 881–2 887.(YAN Yajing,WEN Baoping,HUANG Zhiquan,et al. Effect of soluble salt on the shear strength of unsaturated remodeled loess in Lanzhou[J]. Rock and Soil Mechanics,2017,38(10):2 881–2 887.(in Chinese)) [23] 赵庆玉,张爱军,王毓国,等. 易溶盐含量对原状非饱和伊犁黄土强度的影响[J]. 西北农林科技大学学报:自然科学版,2019,47(4):146–154.(ZHAO Qingyu,ZHANG Aijun,WANG Yuguo,et al. Effect of soluble salt content on the strength of undisturbed unsaturated Ili loess[J]. Journal of Northwest A and F University:Natural Science,2019,47 (4):146–154.(in Chinese)) [24] 曹亚鹏,文 桃,米海珍,等. 硫酸盐渍土含水率单次递减条件下的盐胀特性[J]. 岩土力学,2018,39(3):881–888.(CAO Yapeng,WEN Tao,MI Haizhen,et al. Salt expansion characteristics of sulfated saline soil under single decrease of moisture content[J]. Rock and Soil Mechanics,2018,39(3):881–888.(in Chinese)) [25] 柴寿喜,杨宝珠,王晓燕,等. 含盐量对石灰固化滨海盐渍土力学强度影响试验研究[J]. 岩土力学,2008,29(7):1 769–1 772.(CHAI Shouxi,YANG Baozhu,WANG Xiaoyan,et al. Experimental study on the influence of salt content on mechanical strength of lime-solidified coastal saline soil[J]. Rock and Soil Mechanics,2008,29(7):1 769–1 772.(in Chinese)) [26] 文 桃,米海珍,马连生,等. 硫酸盐渍土击实性能及影响因素试验研究[J]. 岩土力学,2015,36(7):1 945–1 952.(WEN Tao,MI Haizhen,MA Liansheng,et al. Experimental study on compaction performance and influencing factors of sulfated soil[J]. Rock and Soil Mechanics,2015,36(7):1 945–1 952.(in Chinese)) [27] 陈伟志,蒋关鲁,王智猛,等. 分级连续加载条件下原状膨胀土固结变形研究[J]. 岩土力学,2014,35(3):710–716.(CHEN Weizhi,JIANG Guanlu,WANG Zhimeng,et al. Research on consolidation deformation of undisturbed expansive soil under graded continuous loading[J]. Rock and Soil Mechanics,2014,35(3):710–716.(in Chinese)) [28] 王 欢,陈 群,王红鑫,等. 不同压实度和基质吸力的粉煤灰三轴试验研究[J]. 岩土力学,2019,40(增1):224–230.(WANG Huan,CHEN Qun,WANG Hongxin,et al. Triaxial test of fly ash with different degrees of compaction and matrix suction[J]. Rock and Soil Mechanics,2019,40(Supp.1):224–230.(in Chinese)) [29] 陈仲颐,周景星,王洪瑾. 土力学[M]. 北京:清华大学出版社,2008:178–182.(CHEN Zhongyi,ZHOU Jingxing,WANG Hongjin. Soil mechanics[M]. Beijing:Tsinghua University Press,2008:178–182.(in Chinese)) |
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