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| Study on the strength and leaching characteristics of solidified/stabilized lead,zinc and cadmium contaminated soil with red mud-based curing agent |
| GUO Mingshuai,PAN Hao,WANG Fei |
| (Institute of Geotechnical Engineering,Southeast University,Nanjing,Jiangsu 210096,China) |
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Abstract Red mud-phosphogypsum-cement(RPPC),red mud-phosphogypsum-quick lime(RPCA) and ordinary cement(PC) were used to solidify/stabilize the artificially prepared lead,zinc,and cadmium contaminated soil. Then the ratio of red mud-based curing agent was optimized. After the samples were cured for 7 days and 28 days respectively,unconfined compressive strength,toxic leaching test and pH gradient test were carried out. The research results show that with the increase of curing agent content and curing age,the unconfined compressive strength of the samples cured with red mud-based curing agents gradually increases. The difference between the strengths gradually increases. The pH of the leaching solution of the samples cured by the three curing agents are in the range of 7–9. After 28 d curing age,the red mud-based curing agents with 15% content have good strength and curing effect. In comparison,RPPC has better solidifying/stabilizing effect than RPCA. And RPPC has higher unconfined compressive strength and lower heavy metal leaching concentration. The pH gradient test results show that the leaching concentration of heavy metals in RPPC solidified samples was the lowest when pH = 8. Under different pH values of the extractant,the leaching concentration still meets the trend of increasing with the increase of the content.
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| [1] 中华人民共和国环境保护部,中华人民共和国国土资源部. 全国土壤污染状况调查公报[R]. [S. l.]:[s. n.],2014.(Ministry of Environmental Protection of the People?s Republic of China,Ministry of Land and Resources of the People?s Republic of China. Communiqué on the Investigation of National Soil Pollution[R]. [S. l.]:[s. n.],2014.(in Chinese))
[2] 中华人民共和国生态环境部. 中国生态环境状态公报[R]. [S. l.]:[s. n.],2019.(Ministry of Ecology and Environment of the People?s Republic of China. Bulletin of the State of Ecological Environment in China[R]. [S. l.]:[s. n.],2019.(in Chinese))
[3] 王 婷,常高峰. 重金属污染土壤现状与修复技术研究进展[J]. 环境与发展,2017,29(1):33–36.(WANG Ting,CHANG Gaofeng. Present situation and remediation technology research progress for heavy metal contaminated soil[J]. Inner Mongolia Environmental Sciences,2017,29(1):33–36.(in Chinese))
[4] 李 冬,潘利祥,赵良庆,等. 赤泥综合利用的研究进展[J]. 环境工程,2014,32(增1):616–618.(LI Dong,PAN Lixing,ZHAO Liangqing,et al. Advance research of utilization technology of red mud[J]. Environmental Engineering,2014,32(Supp.1):616–618.(in chinese))
[5] 韩 毅. 赤泥吸附材料的制备及应用研究[硕士学位论文][D]. 北京:北京化工大学,2004.(HAN Yi. Study on preparation and application of rud mud adsorbent material[M. S. Thesis][D]. Beijing:Beijing University of Techonlogy,2004.(in Chinese))
[6] 刘昭兵,纪雄辉,王国祥,等. 赤泥对Cd污染稻田水稻生长及吸收累积Cd的影响[J]. 农业环境科学学报,2010,29(4):692–697.(LIU Zhaobing,JI Xionghui,WANG Guoxiang,et al. Effects of red–mud on rice growth and cadmium uptake in cadmium polluted soil[J]. Journal of Agri–Environment Science,2010,29(4):692–697.(in Chinese))
[7] KILINCKALE F,AYHAN S,APAK R. Solidification/stabilization of heavy metal–loaded red muds and fly ashes[J]. Journal of Chemical Technology and Biotechnology,1997,69(2):240–246.
[8] LEE S H,KIM E Y,PARK H,et al. In situ stabilization of arsenic and metal–contaminated agricultural soil using industrial by–products[J]. Geoderma,2011,161(112):1–7.
[9] 李瑞龙,夏素兰,朱家骅,等. 磷石膏与粉煤灰用于钻井废泥浆固化处理的实验研究[J]. 石油与天然气化工,2005,34(3):225–227.(LI Ruilong,XIA Sulan,ZHU Jiahua,et al. The experimental investigation of drilling waste slurries solidification with phosphogypsum and cinder ash[J]. Chemical Engineering of Oil and Gas,2005,34(3):225–227.(in Chinese))
[10] 丁建文,张 帅,洪振舜,等. 水泥–磷石膏双掺固化处理高含水率疏浚淤泥试验研究[J]. 岩土力学,2010,31(9):2 817–2 822.(DING Jianwen,ZHANG Shuai,HONG Zhenshun,et al. Experimental study of solidification of dredged clays with high water content by adding cement and phosphogypsum synchronously[J]. Rock and Soil Menhanics,2010,31(9):2 817–2 822.(in Chinese))
[11] PANTAZOPOULOU E,ZEBILIADOU O,NOLI F,et al. Utilization of phosphogypsum in tannery sludge stabilization and evaluation of the radiological impact[J]. Bulletin of Environmental Contamination and Toxicology,2015,94(3):352–357.
[12] 王 力. 利用磷石膏、粉煤灰和电石渣固化城市污水处理厂污泥试验研究[硕士学位论文][D]. 重庆:重庆大学,2012.(WANG Li. Experimental study on solidification of municipal sewage treatment plant sludge with phosphogypsum,fly ash and calcium carbide slag[M. S. Thesis][D]. Chongqing:Chongqing University,2012.(in Chinese))
[13] SHIN W,KIM Y K. Stabilization of heavy metal contaminated marine sediments with red mud and apatite composite[J]. Journal of Soils and Sediments,2016,16(2):726–735.
[14] CUISINIER O,LE BORGNE T,DENEELE D,et al. Quantification of the effects of nitrates,phosphates and chlorides on soil stabilization with lime and cement[J]. Engineering Geology,2011,117(3/4):229–235.
[15] DU Y J,WEI M L,REDDY K R,et al. New phosphate–based binder for stabilization of soils contaminated with heavy metals:leaching,strength and microstructure characterization[J]. Journal of Environmental Management,2014,146:179–188.
[16] US EPA T. EPA method 1311[R]. Washington,United States:[s. n.],1990.
[17] 陈 蕾,刘松玉,杜延军,等. 水泥固化重金属铅污染土的强度特性研究[J]. 岩土工程学报,2010,32(12):1 898–1 903.(CHEN Lei,LIU Songyu,DU Yanjun,et al. Unconfined compressive strength properties of cement solidified/stabilized lead–contaminated soils[J]. Chinese Journal of Geotechnical Engineering,2010,32(12):1 898–1 903.(in Chinese))
[18] 石云兴,王泽云,吴 东,等. 钙矾石的形成条件与稳定性[J]. 混凝土,2000,(8):52–54.(SHI Yunxing,WANG Zeyun,WU dong,et al. Forming condition and stability of ettringite[J]. Concrete,2000,(8):52–54.(in Chinese))
[19] 彭家惠,张建新,白 冷,等. 矿渣改性硬石膏基胶结材水化硬化研究[J]. 同济大学学报:自然科学版,2009,37(7):934–937.(PENG Jiahui,ZHANG Jianxin,BAI Leng,et al. Hydration and hardening characteristics of anhydrite binder modified with slag[J]. Journal of Tongji University:Natural Science,2009,37(7):934–937.(in Chinese))
[20] 程 钰,李 辰,孙兆云. 水泥基固化剂固化赤泥的路用特性研究[J]. 轻金属,2017,(9):15–18.(CHENG Yu,LI Chen,SUN Zhaoyun. Study on road characteristics of red mud cured with cement-based curing agent[J]. Light Metals,2017,(9):15–18.(in Chinese))
[21] US EPA T. EPA method 9100:Saturated hydraulic conductivity, saturated leachate conductivity,and intrinsic permeability[R]. Bristol,United States:[s. n.],1986.
[22] 魏建宏,罗 琳,刘 艳,等. 赤泥颗粒和赤泥对污染土壤镉形态分布及水稻吸收的效应[J]. 农业环境科学学报,2012,31(2):318–324.(WEI Jianhong,LUO Lin,LIU Yan,et al. Effects of red mud granules and red mud on the distribution of cd fractions and cd uptake by the paddy rice in a contaminated soil[J]. Journal of Agro-Environment Science,2012,31(2):318–324.(in Chinese))
[23] HACKBARTH K,GESING T M,FECHTELKORD M,et al. Synthesis and crystal structure of carbonate cancrinite Na–8 AlSiO4 (6)CO3(H2O)(3.4),grown under low–temperature hydrothermal conditions[J]. Microporous and Mesoporous Materials,1999,30(2/3):347–358.
[24] TSAKIRIDIS P E,AGATZINI–LEONARDOU S,OUSTADAKIS P. Red mud addition in the raw meal for the production of Portland cement clinker[J]. Journal of Hazardous Materials,2004,116(1/2):103–110.
[25] 罗惠莉. 赤泥改性颗粒修复材料及其对铅锌污染土壤的原位稳定化研究[博士学位论文][D]. 长沙:中南大学,2012.(LUO Huili. In-situ stabilization of Pb–Zn contaminated soil using modified red mud granules[Ph. D. Thesis][D]. Changsha:Central South University,2012.(in Chinese))
[26] 章定文,项 莲,曹智国. CaO对钙矾石固化/稳定化重金属铅污染土的影响[J]. 岩土力学,2018,39(1):29–35.(ZHANG Dingwen,XIANG Lian,CAO Zhiguo. Effect of CaO on ettringite stabilization/solidification of lead–contaminated soil[J]. Rock and Soil Mechanics,2018,39(1):29–35.(in Chinese))
[27] SANTONA L,CASTALDI P,MELIS P. Evaluation of the interaction mechanisms between red muds and heavy metals[J]. Journal of Hazardous Materials,2006,136(2):324–329.
[28] 李 慧. 赤泥基钝化剂对镉污染稻田修复成效研究及安全性评价 [博士学位论文][D]. 长沙:湖南农业大学,2018.(LI Hui. Remediation effects and safety evaluation of red mud based passivator on Cd–contaminated paddy field[Ph. D. Thesis][D]. Changsha:Hunan Agricultural University,2018.(in Chinese))
[29] 权娟娟,张凯峰,马 斌. 磷渣替代矿渣对水泥孔溶液pH值及水化进程的影响[J]. 硅酸盐通报,2016,5(8):2 513–2 517.(QUAN Juanjuan,ZHANG Kaifeng,MA Bin. Effect of pore solution ph value、and hydration process on phosphorous slag replacing of slag[J]. Bulletin of the Chinese Ceramic Society,2016,35(8):2 513–2 517.(in Chinese))
[30] 陈 蕾. 水泥固化稳定重金属污染土机理与工程特性研究[博士学位论文][D]. 南京:东南大学,2010.(CHEN Lei. Research of mechanism and properties of cement stabilized/solidified heavy metal contaminated soils[Ph. D. Thesis][D]. Nanjing:Southeast University,2010.(in Chinese))
[31] 魏明俐. 新型磷酸盐固化剂固化高浓度锌铅污染土的机理及长期稳定性试验研究[博士学位论文][D]. 南京:东南大学,2017.(WEI Mingli. Research of mechamism and long–term performance of a new phosphate–based binder for stabilization of soils contaminated with high levels of zinc and lead[Ph. D. Thesis][D]. Nanjing:Southeast University,2017.(in Chinese))
[32] 项 莲. 基于钙矾石的重金属污染土固化/稳定化条件构建与机制探讨[硕士学位论文][D]. 南京:东南大学,2018.(Xiang Lian. The conditional construction and mechanism based on ettringite stabilization/solidified heavy metal contaminated soils[M. S. Thesis][D]. Nanjing:Southeast University,2018.(in Chinese))
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