|
|
|
| Water retention characteristics of GMZ bentonite with different montmorillonite contents and dry densities |
| ZHANG Qi1, 2*, WANG Ju1, LIU Jiangfeng2, ZONG Zihua1, CAO Shengfei1, XIE Jingli1, CHENG Jianfeng1 |
| (1. CAEA Innovation Center for Geological Disposal of High-Level Radioactive Waste, Beijing Research Institute of Uranium Geology, Beijing 100029, China; 2. State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China) |
|
|
|
|
Abstract The investigation of the water retention characteristics of Gaomiaozi (GMZ) bentonite is crucial for selecting buffer/backfill materials and designing engineering barrier systems for high-level radioactive waste (HLW) geological disposal. This study examined the water retention properties of GMZ bentonite with varying montmorillonite contents and dry densities. The Nuclear Magnetic Resonance (NMR) technique was utilized to analyze the microscopic characteristics and mechanisms of water distribution in GMZ bentonite under different conditions. The results indicated that the effect of montmorillonite content on the water retention properties of GMZ bentonite was dependent on the controlled suction during the tests. When the controlled suction was below 113.8 MPa, the volumetric change rate and water content of the samples increased gradually with higher montmorillonite content. However, no significant correlation was found between increases in montmorillonite content and volumetric change rate or water content at controlled suctions exceeding 113.8 MPa. Throughout the suction range of 2.7 MPa to 367.8 MPa investigated in this study, the dry density of GMZ bentonite did not significantly influence its water retention characteristics. The water retention curves of GMZ bentonite with varying montmorillonite contents and dry densities were well fitted by the Van Genuchten model. Finally, NMR tests were conducted on samples following the water retention tests, which confirmed the findings obtained from the water retention characteristic tests of GMZ bentonite.
|
|
|
|
|
|
[1] 王 驹,陈伟明,苏 锐,等. 高放废物地质处置及其若干关键科学问题[J]. 岩石力学与工程学报,2006,25(4):801–812.(WANG Ju,CHEN Weiming,SU Rui,et al. Geological disposal of high-level radioactive waste and its key scientific issues[J]. Chinese Journal of Rock Mechanics and Engineering,2006,25(4):801–812.(in Chinese))
[2] 井兰如,冯夏庭. 放射性废物地质处置中主要岩石力学问题[J]. 岩石力学与工程学报,2006,25(4):833–841.(JING Lanru,FENG Xiating. Main rock mechanics issues in geological disposal of radioactive wastes[J]. Chinese Journal of Rock Mechanics and Engineering,2006,25(4):833–841.(in Chinese))
[3] 王 驹,陈 亮,周志超,等. 我国高放废物地质处置新突破[J]. 原子能科学技术,2024,58(增2):217–230.(WANG Ju,CHEN Liang,ZHOU Zhichao,et al. Geological disposal of high level radioactive waste in China:progress and breakthrough during 2019–2024[J]. Atomic Energy Science and Technology,2024,58(Supp.2):217–230.(in Chinese))
[4] 王 驹,苏 锐,陈 亮,等. 中国高放废物地质处置地下实验室场址筛选[J]. 世界核地质科学,2022,39(1):1–13.(WANG Ju,SU Rui,CHEN Liang,et al. Site selection of underground research laboratory for geological disposal of high-level radioactive waste in China[J]. World Nuclear Geoscience,2022,39(1):1–13.(in Chinese))
[5] WANG J,CHEN L,SU R,et al. The Beishan underground research laboratory for geological disposal of high-level radioactive waste in China:planning,site selection,site characterization and in situ tests[J]. Journal of Rock Mechanics and Geotechnical Engineering,2018,10(3):411–435.
[6] 刘月妙,陈璋如. 内蒙古高庙子膨润土作为高放废物处置库回填材料的可行性[J]. 矿物学报,2001,21(3):541–543.(LIU Yuemiao,CHEN Zhangru. Bentonite from Gaomiaozi,Inner Mongolia as an ideal buffer/ backfilling material in handling highly radioactive wastes—A feasibility study[J]. Acta Mineralogica Sinica,2001,21(3):541–543.(in Chinese))
[7] 刘月妙,徐国庆,刘淑芬,等. 我国高放废物处置库缓冲/回填材料压实膨胀特性研究[J]. 铀矿地质,2001,17(1):44–47.(LIU Yuemiao,XU Guoqing,LIU Shufen,et al. Study on compactibility and swelling property of buffer/backfill material for HLW repository[J]. Uranium Geology,2001,17(1):44–47.(in Chinese))
[8] 刘月妙,徐国庆,刘淑芬. 高放废物地质处置库缓冲/回填材料性能测定[J]. 辐射防护,1998,18(4):52–57.(LIU Yuemiao,XU Guoqing,LIU Shufen. A study on buffer/backfill materials for HLW geological repository[J]. Radiation Protection,1998,18(4):52–57.(in Chinese))
[9] 谢敬礼,曹胜飞,高玉峰,等. 高庙子膨润土矿勘探与钠基膨润土开采[J]. 中国矿业,2018,27(2):125–129.(XIE Jingli,CAO Shengfei,GAO Yufeng,et al. Exploration of Gaomiaozi bentonite deposit and excavation of the natural sodium bentonite[J]. China Mining Magazine,2018,27(2):125–129.(in Chinese))
[10] 谢敬礼,马利科,高玉峰,等. 北山花岗岩岩屑–膨润土混合材料导热性能研究[J]. 岩土力学,2018,39(8):2 823–2 828.(XIE Jingli,MA Like,GAO Yufeng,et al. Thermal conductivity of mixtures of Beishan bentonite and crushed granite[J]. Rock and Soil Mechanics,2018,39(8):2 823–2 828.(in Chinese))
[11] 谈云志,彭 帆,钱芳红,等. 石墨–膨润土缓冲材料的最优配置方法[J]. 岩土力学,2019,40(9):3 387–3 396.(TAN Yunzhi,PENG Fan,QIAN Fanghong,et al. Optimal mixed scheme of graphite-bentonite buffer material[J]. Rock and Soil Mechanics,2019,40(9):3 387–3 396.(in Chinese))
[12] 叶为民,钱丽鑫,陈 宝,等. 侧限状态下高压实高庙子膨润土非饱和渗透性的试验研究[J]. 岩土工程学报,2009,31(1):105–108.(YE Weimin,QIAN Lixin,CHEN Bao,et al. Laboratory test on unsaturated hydraulic conductivity of densely compacted Gaomiaozi bentonite under confined conditions[J]. Chinese Journal of Geotechnical Engineering,2009,31(1):105–108.(in Chinese))
[13] 秦 冰,陈正汉,刘月妙,等. 高庙子膨润土GMZ001三向膨胀力特性研究[J]. 岩土工程学报,2009,31(5):756–763.(QIN Bing,CHEN Zhenghan,LIU Yuemiao,et al. Characteristics of 3D swelling pressure of GMZ001 bentonite[J]. Chinese Journal of Geotechnical Engineering,2009,31(5):756–763.(in Chinese))
[14] 张虎元,崔素丽,刘吉胜,等. 混合型缓冲回填材料膨胀力试验研究[J]. 岩土力学,2010,31(10):3 087–3 095.(ZHANG Huyuan,CUI Suli,LIU Jisheng,et al. Experimental study of swelling pressure of compacted bentonite-sand mixture[J]. Rock and Soil Mechanics,2010,31(10):3 087–3 095.(in Chinese))
[15] 张 龙,孙德安,刘月妙. 两种高庙子钠基膨润土膨胀特性比较研究[J]. 岩土力学,2016,37(12):3 447–3 454.(ZHANG Long,SUN Dean,LIU Yuemiao. Comparison between swelling properties of two Gaomiaozi Na-bentonites[J]. Rock and Soil Mechanics,2016,37(12):3 447–3 454.(in Chinese))
[16] 项国圣,方 圆,徐永福. 阳离子交换对高庙子钠基膨润土膨胀性能的影响[J]. 浙江大学学报:工学版,2017,51(5):931–936. (XIANG Guosheng,FANG Yuan,XU Yongfu. Swelling characteristics of GMZ01 bentonite affected by cation exchange reaction[J]. Journal of Zhejiang University:Engineering Science,2017,51(5):931–936.(in Chinese))
[17] 张 悦,叶为民,王 琼,等. 含盐遗址重塑土的吸力测定及土水特征曲线拟合[J]. 岩土工程学报,2019,41(9):1 661–1 669. (ZHANG Yue,YE Weimin,WANG Qiong,et al. Suction measurement and SWRC modelling for reconstituted salt-laden soils in earthen heritages[J]. Chinese Journal of Geotechnical Engineering,2019,41(9):1 661–1 669.(in Chinese))
[18] 陈正汉,苗强强,郭 楠,等. 关于持水特性曲线研究的几个问题[J]. 岩土工程学报,2023,45(4):671–679.(CHEN Zhenghan,MIAO Qiangqiang,GUO Nan,et al. On some problems of researches on soil-water retention curve[J]. Chinese Journal of Geotechnical Engineering,2023,45(4):671–679.(in Chinese))
[19] WAN M,YE W M,CHEN Y G,et al. Influence of temperature on the water retention properties of compacted GMZ01 bentonite[J]. Environmental earth sciences,2015,73(8):4 053–4 061.
[20] 陈 宝,钱丽鑫,叶为民,等. 高庙子膨润土的土水特征曲线[J]. 岩石力学与工程学报,2006,25(4):788–793.(CHEN Bao,QIAN Lixin,YE Weimin,et al. Soil-water characteristic curves of Gaomiaozi bentonite[J]. Chinese Journal of Rock Mechanics and Engineering,2006,25(4):788–793.(in Chinese))
[21] 陈永贵,李昆鹏,马 婧,等. 化学作用下高庙子膨润土屏障性能演化行为[J]. 工程地质学报,2022,30(1):71–82.(CHEN Yonggui,LI Kunpeng,MA Jing,et al. Evolution of barrier properties for Gaomiaozi bentonite under chemical effects[J]. Journal of Engineering Geology,2022,30(1):71–82.(in Chinese))
[22] 张小小,陈永贵,李昆鹏,等. 前期化学循环作用下石墨烯改性GMZ膨润土持水特性[J]. 岩土工程学报,2023,45(7):1 490–1 497. (ZHANG Xiaoxiao,CHEN Yonggui,LI Kunpeng,et al. Water retention characteristics of grapheme-modified GMZ bentonite subjected to preliminary chemical cycles[J]. Chinese Journal of Geotechnical Engineering,2023,45(7):1 490–1 497.(in Chinese))
[23] 梁维云,韦昌富,张 芹,等. 膨润土吸湿过程中膨胀力演化及水分分布特征[J]. 岩土工程学报,2023,45(2):283–291.(LIANG Weiyun,WEI Changfu,ZHANG Qin,et al. Swelling pressure evolution and water distribution characteristics of bentonite during wetting process[J]. Chinese Journal of Geotechnical Engineering,2023,45(2):283–291.(in Chinese))
[24] 中华人民共和国行业标准编写组. T/CECS 1337—2023非饱和土试验方法标准[S]. 北京:中国建筑工业出版社,2023.(The Professional Standards Compilation Group of People?s Republic of China. T/CECS 1337—2023 Standard for unsaturated soil testing method[S]. Beijing:China Architecture and Building Press,2023.(in Chinese))
[25] 秦 冰,陈正汉,孙发鑫,等. 高吸力下持水曲线的温度效应及其吸附热力学模型[J]. 岩土工程学报,2012,34(10):1 877–1 886. (QIN Bing,CHEN Zhenghan,SUN Faxin,et al. Temperature effect on water retention curve under high suction and its modeling based on thermodynamics of sorption[J]. Chinese Journal of Geotechnical Engineering,2012,34(10):1 877–1 886.(in Chinese))
[26] SANDEN T,NILSSON U,ANDERSSON L,et al. Investigation of parameters influencing bentonite block quality,laboratory investigation. No. SKB-P-16-06[R]. Stockholm:Swedish Nuclear Fuel and Waste Management Co.,2016.
[27] VAN GENUCHTEN M. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils[J]. Soil Science Society of America Journal,1980,44(5):892–898.
[28] HE Y,YE W M,CHEN Y G,et al. Effects of NaCl solution on the swelling and shrinkage behavior of compacted bentonite under one-dimensional conditions[J]. Bulletin of Engineering Geology and the Environment,2020,79(1):399–410. |
|
|
|