Study on the characteristics of the soil-rock mixture structure based on the high-frequency extremum of the electrochemical impedance spectroscopy
DONG Hui1,2,CHEN Li1,JIANG Xiuzi1,2,DING Yanhuai1
(1. College of Civil Engineering and Mechanics,Xiangtan University,Xiangtan,Hunan 411105,China;2. Hunan Key Laboratory of Geomechanics and Engineering Safety,Xiangtan University,Xiangtan,Hunan 411105,China)
In order to make a preliminary exploration of the unity of the study of soil-rock mixture under different basic materials and different scales,the electrochemical impedance spectroscopy method was used to study the soil-rock mixture composed of ideal materials.Through the macroscopical adjustment of the three materials indexes of the rock-soil mixture system of water content,soil-rock ratio,and particle size,the rules of the electrochemical impedance spectroscopy results were obtained.Based on the high-frequency extremum of the electrochemical impedance spectroscopy(EIS),its regularity was described and further studied.Thus,a preliminary mapping was made between the electron passability at the micro-scale and the material indexes at the macro-scale.A series of concepts and tools such as coupling degree,curve of the impedance¢s extremum(CIE),optimal point of CIE were put forward.The basic effect of water content on the structure of soil-rock mixture was obtained,and the influence of soil-rock ratio is dominated by two factors. Especially with the orderly change of the particle size,its high-frequency extremum moved along curved path.These above research results have some reference value to the study of the structural characteristics of soil-rock mixture.
董 辉1,2,陈 立1,蒋秀姿1,2,丁燕怀1. 基于电化学阻抗谱高频极值的土石混合体结构特征研究[J]. 岩石力学与工程学报, 2017, 36(S2): 4134-4141.
DONG Hui1,2,CHEN Li1,JIANG Xiuzi1,2,DING Yanhuai1. Study on the characteristics of the soil-rock mixture structure based on the high-frequency extremum of the electrochemical impedance spectroscopy. , 2017, 36(S2): 4134-4141.
李 晓,廖秋林,赫建明,等.土石混合体力学特性的原位试验研究[J].岩石力学与工程学报,2007,26(12):2377-2384.(LI Xiao,LIAO Qiulin,HE Jianming,et al.Studyon in-situ tests ofmechanical characteristics on soil-rock aggregate[J].Chinese Journal of Rock Mechanical and Engineering,2007,26(12):2377-2384.(in Chinese))
[2]
ZHU F,YANG Y,CHEN C,et al. Experimental study on slope stability with soil mixed rocks under rainfall[C]//Progress in Civil Engineering. [S. l.]:[s. n.],2012:504-508.
[3]
徐文杰,张海洋.土石混合体研究现状及发展趋势[J].水利水电科技进展,2013,33(1):80-88.(XU Wenjie,ZHANG Haiyang.Research status and development trend of soil-rock mixture[J]. Advances in Science and Technology of Water Resources,2013,33(1):80-88.(in Chinse))
[4]
王宇,李晓,赫建明,等.土石混合体细观特性研究现状及展望[J].工程地质学报,2014,22(1):112-123.(WANG Yu,LI Xiao,He Jianming. Research status and prospect of rock and soil aggregate[J]. Journal of Engineering Geology,2014,22(1):112-123.(in Chinese))
[5]
ZHANG S,TANG H,ZHAN H,et al. Investigation of scale effect of numerical unconfined compression strengths of virtual colluvial-deluvial soil-rock mixture[J]. International Journal of Rock Mechanics and Mining Sciences,2015,77:208-219.
[6]
胡江春,王红芳,何满潮,等.交流阻抗谱法及其在岩石微裂纹检测中的应用[J].岩土工程学报,2007,29(6):853-856.(HU Jiangchun,WANG Hongfang,HE Manchao,et al. Impedance spectroscopy and application to test the microcrack of rock[J]. Chinese Journal of Geotechnical Engineering,2007,29(6):853-856.(in Chinese))
[7]
陈向荣,史美伦,贺鸿珠,等.水硬性胶凝材料水化性质评估的阻抗方法[J].建筑材料学报,2011,14(1):22-25.(CHEN Xiangrong,SHI Meilun,HE Hongzhu,et al. Evaluation of hydration of cementitiousmaterial by impedance technique[J]. Journal of Building Materials,2011,14(1):22-25.(in Chinese))
张文.混凝土水泥水化过程的电化学阻抗谱研究[硕士学位论文][D].大连:大连理工大学,2013.(ZHANG Wen. Study on cement hydrationprocess of concrete by electrochemical impedance spectroscopy[M. S.Thesis][D]. Dalian:Dalian University of technology,2013.(in Chinese))
[10]
何兵.交流阻抗谱监测混凝土膨胀开裂的可行性研究[硕士学位论文][D].重庆:重庆大学,2015.(HE Bing. Research on Feasibility of AC Impedance Monitoring Concrete Expansion and Cracks[M. S.Thesis][D]. Chongqing:ChongqingUniversity,2015.(in Chinese))
[1]
王瑞攀,何富强,安晓鹏,等.粉煤灰水泥基材料交流阻抗谱的弥散效应研究[J].硅酸盐通报,2016,35(6):1877-1882.(WANG Ruipan,HE Fuqiang,AN Xiaopeng,et al. Effect of dispersion of AC impedance spectroscopy of cement-based materials with fly ash[J]. Bulletin of the Chinese Ceramic Society,2016,35(6):1877-1882.(in Chinese))
[2]
史美伦,杨正宏.混凝土阻抗谱的拓扑结构[J].建筑材料学报,2002,5(2):132-136.(SHI Meilun,YANG Zhenghong. Topological structure of the spectroscopy of Ac impedance for concrete[J]. Journal of building materials,2002,5(2):132-136.(in Chinese))